Some new aspects in the application of perfluoroalkyl halides in the synthesis of fluorine-containing organic compounds Full article
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Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837 |
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| Output data | Year: 2000, Volume: 69, Number: 6, Pages: 491-522 Pages count : DOI: 10.1070/RC2000v069n06ABEH000353 | ||
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Abstract:
The approaches to the activation of perfluoroalkyl halides used as intermediates in the synthesis of partially fluorinated compounds are considered. The conditions for reactions of organic compounds with perfluoroalkyl iodides in the presence of reductants (Na2S2O4, HOCH2SO2Na), metals and metal salts, redox systems (Na2S2O8, ButOOH, Pb(OAc)4, H2O2-FeSO4, Ce(SO4)2) and transition metal complexes are described. The generation of perfluoroalkyl radicals by a single-electron transfer mechanism are discussed. The introduction of perfluoroalkyl groups into aromatic and unsaturated organic compounds and functionalisation of perfluoroalkyl iodides, particularly, their transformation into perfluoroalkanesulfinic and perfluoroalkanecarboxylic acids and aldehydes, are considered. The bibliography includes 442 references.
Cite:
Furin G.G.
Some new aspects in the application of perfluoroalkyl halides in the synthesis of fluorine-containing organic compounds
Russian Chemical Reviews. 2000. V.69. N6. P.491-522. DOI: 10.1070/RC2000v069n06ABEH000353 Scopus РИНЦ OpenAlex
Some new aspects in the application of perfluoroalkyl halides in the synthesis of fluorine-containing organic compounds
Russian Chemical Reviews. 2000. V.69. N6. P.491-522. DOI: 10.1070/RC2000v069n06ABEH000353 Scopus РИНЦ OpenAlex
Original:
Furin G.G.
Novel aspects of perfluoroalkyl halide application to the synthesis of fluorine-containing organic compounds
Успехи химии/Uspekhi Khimii. 2000. V.69. N6. P.538-571. РИНЦ
Novel aspects of perfluoroalkyl halide application to the synthesis of fluorine-containing organic compounds
Успехи химии/Uspekhi Khimii. 2000. V.69. N6. P.538-571. РИНЦ
Dates:
| Published print: | Jun 30, 2000 |
| Published online: | Oct 17, 2007 |
Identifiers:
| Scopus: | 2-s2.0-0003257086 |
| Elibrary: | 13351866 |
| OpenAlex: | W2081874183 |