Reaction of Triethyl Phosphite with Internal Perfluoroolefins and Their Aza Analogs Научная публикация
| Журнал |
Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350 |
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| Вых. Данные | Год: 1998, Том: 68, Номер: 5, Страницы: 753-760 Страниц : | ||
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Реферат:
Treatment of perfluoro(2-methylpent-2-ene) with triethyl phosphite gave triethoxydifluorophosphorane and diethyl perfluoro(1-ethylidene-2-methylpropenyl)phosphonate (the latter was also obtained by reaction of triethyl phosphite with perfluorotrimethylallene), while the reactions with other unsaturated perfluorinated compounds involved, together with the Arbuzov reaction, replacement of fluorine at the double bound by an ethyl group with perfluoro(1-ethylcyclohex-1-ene) and by an ethoxy group with perfluoro-(5-azanon-4-ene), perfluoro(1-azacyclohex-1-ene), and perfluoro(3-azapent-2-ene). The reactions pathways and 1H, 13C, 19F, and 31P NMR data are discussed.
Библиографическая ссылка:
Rogoza A.V.
, Furin G.G.
Reaction of Triethyl Phosphite with Internal Perfluoroolefins and Their Aza Analogs
Russian Journal of General Chemistry. 1998. V.68. N5. P.753-760. Scopus РИНЦ
Reaction of Triethyl Phosphite with Internal Perfluoroolefins and Their Aza Analogs
Russian Journal of General Chemistry. 1998. V.68. N5. P.753-760. Scopus РИНЦ
Идентификаторы БД:
| Scopus: | 2-s2.0-0032342114 |
| РИНЦ: | 13298799 |