Reaction of Triethyl Phosphite with Internal Perfluoroolefins and Their Aza Analogs

Reaction of Triethyl Phosphite with Internal Perfluoroolefins and Their Aza Analogs Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 1998, Volume: 68, Number: 5, Pages: 753-760 Pages count :

Authors

Rogoza A. V. , Furin G. G.

Affiliations

1	(Scopus) Novosibirsk Inst. of Organ. Chem., Siberian Division, Russian Academy of Sciences, Novosibirsk, Russian Federation

Treatment of perfluoro(2-methylpent-2-ene) with triethyl phosphite gave triethoxydifluorophosphorane and diethyl perfluoro(1-ethylidene-2-methylpropenyl)phosphonate (the latter was also obtained by reaction of triethyl phosphite with perfluorotrimethylallene), while the reactions with other unsaturated perfluorinated compounds involved, together with the Arbuzov reaction, replacement of fluorine at the double bound by an ethyl group with perfluoro(1-ethylcyclohex-1-ene) and by an ethoxy group with perfluoro-(5-azanon-4-ene), perfluoro(1-azacyclohex-1-ene), and perfluoro(3-azapent-2-ene). The reactions pathways and 1H, 13C, 19F, and 31P NMR data are discussed.

Rogoza A.V. , Furin G.G.
Reaction of Triethyl Phosphite with Internal Perfluoroolefins and Their Aza Analogs
Russian Journal of General Chemistry. 1998. V.68. N5. P.753-760. Scopus РИНЦ

Scopus:	2-s2.0-0032342114
Elibrary:	13298799

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