Synthesis of azetine derivatives from perfluoro(2-methyl-2-pentene) and some primary amines

Synthesis of azetine derivatives from perfluoro(2-methyl-2-pentene) and some primary amines Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Вых. Данные

Год: 2000, Том: 36, Номер: 1, Страницы: 99-104 Страниц : 6

Авторы

Furin G.G. ¹ , Lopyrev V.A. ² , Zhuzhgov E.L. ³ , Protsuk N.I. ²

Организации

1	(Scopus) Vorozhtsov Novosibirsk Inst. of O., Siberian Division, Russian Academy of Sciences, pr. Lavrent'eva 9, Novosibirsk, 630090, Russian Federation
2	(Scopus) Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russian Federation
3	(Scopus) Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russian Federation

Reactions of perfluoro(2-methyl-2-pentene) with isopropylamine and tert-butylamine in acetonitrile in the presence of triethylamine gave, respectively, isopropyl-and tert-butyl(heptafluoro-2-trifluoromethyl-1-pentenylidene)amines which were converted into azetine derivatives. Reactions of perfluoro-(2-methyl-2-pentene) with 2-amino-6-bromobenzothiazole and 2-amino-1-methylbenzimidazole yielded 4,4-difluoroazetine derivatives. Possible reaction pathways, role of triethylamine, and factors influencing the intramolecular nucleophilic cyclization are discussed.

Furin G.G. , Lopyrev V.A. , Zhuzhgov E.L. , Protsuk N.I.
Synthesis of azetine derivatives from perfluoro(2-methyl-2-pentene) and some primary amines
Russian Journal of Organic Chemistry. 2000. V.36. N1. P.99-104. Scopus РИНЦ

Furin G.G. , Lopyrev V.A. , Zhuzhgov E.L. , Protsuk N.I.
Synthesis of azetine derivatives based on perfluoro-2-methyl-2-pentene and certain primary amines
Журнал органической химии (RUSS J ORG CHEM+). 2000. V.36. N1. P.109-115. WOS

Scopus:	2-s2.0-0033632779
РИНЦ:	13359316

БД	Цитирований
Scopus	7
РИНЦ	7