Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride, Part 1. Oxygenation of [C6F5Xe]+ [AsF6]- and epoxidation of fluorinated cycloalkenylxenon(II) salts Научная публикация
| Журнал |
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
ISSN: 0932-0776 |
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| Вых. Данные | Год: 1996, Том: 51, Номер: 7, Страницы: 1011-1014 Страниц : 4 DOI: 10.1515/znb-1996-0717 | ||||
| Ключевые слова | (Pentafluoro-1,4-cyclohexadien-3-on-1-yl)-xenon(II); (Pentafluoro-4,5-epoxycyclohexen-3-on-1-yl)xenon(II); (Pentafluorophenyl)xenon(II); Electrophilic oxygenation; Xenon difluoride | ||||
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Реферат:
XeF2 and H2O react with [C6F5Xe]+ [AsF6]- in HF without Xe-C bond cleavage under formation of the cyclohexadienone compound [3-O-1,4-C6F5Xe]+ [AsF6]-. The FC=CF moiety in this dienone is epoxidised with the same reagent. The cyclohexadiene compound [1,4-C6F7Xe]+ [AsF6]- could also be epoxidised under the same conditions.
Библиографическая ссылка:
Frohn H.J.
, Bardin V.V.
Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride, Part 1. Oxygenation of [C6F5Xe]+ [AsF6]- and epoxidation of fluorinated cycloalkenylxenon(II) salts
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1996. V.51. N7. P.1011-1014. DOI: 10.1515/znb-1996-0717 WOS Scopus OpenAlex
Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride, Part 1. Oxygenation of [C6F5Xe]+ [AsF6]- and epoxidation of fluorinated cycloalkenylxenon(II) salts
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1996. V.51. N7. P.1011-1014. DOI: 10.1515/znb-1996-0717 WOS Scopus OpenAlex
Даты:
| Опубликована в печати: | 1 июл. 1996 г. |
| Опубликована online: | 2 июн. 2014 г. |
Идентификаторы БД:
| Web of science: | WOS:A1996VB44700017 |
| Scopus: | 2-s2.0-0038971344 |
| OpenAlex: | W2313353586 |