Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride, Part 1. Oxygenation of [C6F5Xe]+ [AsF6]- and epoxidation of fluorinated cycloalkenylxenon(II) salts Full article
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Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
ISSN: 0932-0776 |
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| Output data | Year: 1996, Volume: 51, Number: 7, Pages: 1011-1014 Pages count : 4 DOI: 10.1515/znb-1996-0717 | ||||
| Tags | (Pentafluoro-1,4-cyclohexadien-3-on-1-yl)-xenon(II); (Pentafluoro-4,5-epoxycyclohexen-3-on-1-yl)xenon(II); (Pentafluorophenyl)xenon(II); Electrophilic oxygenation; Xenon difluoride | ||||
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Abstract:
XeF2 and H2O react with [C6F5Xe]+ [AsF6]- in HF without Xe-C bond cleavage under formation of the cyclohexadienone compound [3-O-1,4-C6F5Xe]+ [AsF6]-. The FC=CF moiety in this dienone is epoxidised with the same reagent. The cyclohexadiene compound [1,4-C6F7Xe]+ [AsF6]- could also be epoxidised under the same conditions.
Cite:
Frohn H.J.
, Bardin V.V.
Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride, Part 1. Oxygenation of [C6F5Xe]+ [AsF6]- and epoxidation of fluorinated cycloalkenylxenon(II) salts
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1996. V.51. N7. P.1011-1014. DOI: 10.1515/znb-1996-0717 WOS Scopus OpenAlex
Electrophilic oxygenation with XeF2 - H2O in hydrogen fluoride, Part 1. Oxygenation of [C6F5Xe]+ [AsF6]- and epoxidation of fluorinated cycloalkenylxenon(II) salts
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 1996. V.51. N7. P.1011-1014. DOI: 10.1515/znb-1996-0717 WOS Scopus OpenAlex
Dates:
| Published print: | Jul 1, 1996 |
| Published online: | Jun 2, 2014 |
Identifiers:
| Web of science: | WOS:A1996VB44700017 |
| Scopus: | 2-s2.0-0038971344 |
| OpenAlex: | W2313353586 |