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Stereoselectivity of formation of monoterpene - Amino acids hybrid molecules in the reaction of monoterpene nitroso chlorides with alpha-amino acid derivatives Научная публикация

Журнал Steroids
ISSN: 0039-128X , E-ISSN: 1878-5867
Вых. Данные Год: 2017, Том: 117, Номер: SI, Страницы: 112-119 Страниц : 8 DOI: 10.1016/j.steroids.2016.09.016
Ключевые слова Amino acids; (+)-3-Carene; (-)-alpha-Pinene; Nitroso chlorides; Diastereoselectivity
Авторы Marenin K.S. 1 , Gatilov Yu.V. 1 , Agafontsev A.M. 1 , Tkachev A.V. 1,2
Организации
1 (Данные Web of science) NN Vorozhtsov Novosibirsk Inst Organ Chem, Novosibirsk 630090, Russia
2 (Данные Web of science) Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia

Реферат: Reaction of nitrosochlorides of natural monoterpene hydrocarbons (+)-3-carene and (-)-alpha-pinene with L-amino acids and their methyl esters results in stereoselective formation of terpene-amino acids hybrids, which belong to the series of alpha-substituted amino oximes. The reaction with an excess of racemic DL-amino acids and their derivatives induces partial resolution of the amino acid components and formation of the diastereomeric mixtures of the terpene-amino acids hybrids, with diastereomeric excess varying from 0 to 100%. (C) 2016 Elsevier Inc. All rights reserved.
Библиографическая ссылка: Marenin K.S. , Gatilov Y.V. , Agafontsev A.M. , Tkachev A.V.
Stereoselectivity of formation of monoterpene - Amino acids hybrid molecules in the reaction of monoterpene nitroso chlorides with alpha-amino acid derivatives
Steroids. 2017. V.117. NSI. P.112-119. DOI: 10.1016/j.steroids.2016.09.016 WOS Scopus РИНЦ OpenAlex
Даты:
Опубликована в печати: 1 янв. 2017 г.
Идентификаторы БД:
Web of science: WOS:000392566800016
Scopus: 2-s2.0-85006753312
РИНЦ: 29466566
OpenAlex: W2526253820
Цитирование в БД:
БД Цитирований
Web of science 3
Scopus 4
РИНЦ 5
OpenAlex 3
Альметрики: