Stereoselectivity of formation of monoterpene - Amino acids hybrid molecules in the reaction of monoterpene nitroso chlorides with alpha-amino acid derivatives Full article
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Steroids
ISSN: 0039-128X , E-ISSN: 1878-5867 |
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| Output data | Year: 2017, Volume: 117, Number: SI, Pages: 112-119 Pages count : 8 DOI: 10.1016/j.steroids.2016.09.016 | ||||
| Tags | Amino acids; (+)-3-Carene; (-)-alpha-Pinene; Nitroso chlorides; Diastereoselectivity | ||||
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Abstract:
Reaction of nitrosochlorides of natural monoterpene hydrocarbons (+)-3-carene and (-)-alpha-pinene with L-amino acids and their methyl esters results in stereoselective formation of terpene-amino acids hybrids, which belong to the series of alpha-substituted amino oximes. The reaction with an excess of racemic DL-amino acids and their derivatives induces partial resolution of the amino acid components and formation of the diastereomeric mixtures of the terpene-amino acids hybrids, with diastereomeric excess varying from 0 to 100%. (C) 2016 Elsevier Inc. All rights reserved.
Cite:
Marenin K.S.
, Gatilov Y.V.
, Agafontsev A.M.
, Tkachev A.V.
Stereoselectivity of formation of monoterpene - Amino acids hybrid molecules in the reaction of monoterpene nitroso chlorides with alpha-amino acid derivatives
Steroids. 2017. V.117. NSI. P.112-119. DOI: 10.1016/j.steroids.2016.09.016 WOS Scopus РИНЦ OpenAlex
Stereoselectivity of formation of monoterpene - Amino acids hybrid molecules in the reaction of monoterpene nitroso chlorides with alpha-amino acid derivatives
Steroids. 2017. V.117. NSI. P.112-119. DOI: 10.1016/j.steroids.2016.09.016 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Jan 1, 2017 |
Identifiers:
| Web of science: | WOS:000392566800016 |
| Scopus: | 2-s2.0-85006753312 |
| Elibrary: | 29466566 |
| OpenAlex: | W2526253820 |