Catalytic epoxidation of 3-carene and limonene with aqueous hydrogen peroxide, and selective synthesis of α-pinene epoxide from turpentine Научная публикация
| Журнал |
Catalysts
ISSN: 2073-4344 |
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| Вых. Данные | Год: 2021, Том: 11, Номер: 4, Номер статьи : 436, Страниц : DOI: 10.3390/catal11040436 | ||
| Ключевые слова | 3-carene; 3-carene epoxide; Aqueous hydrogen peroxide; Epoxidation; Limo-nene; Limonene diepoxide; Turpentine; α-pinene; α-pinene epoxide | ||
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Реферат:
The epoxidation of turpentine (technical α-pinene), 3-carene, and limonene with aqueous hydrogen peroxide was studied in a new catalytic system employing manganese sulfate, salicylic acid, sodium bicarbonate, and acetonitrile, as a polar solvent. The proposed approach makes it possible to carry out a “chemical separation” of turpentine components, yielding valuable individual derivatives of monoterpenes without the need to isolate individual monoterpene reagents. Specific methods have been developed for the production of α-pinene epoxide, 3-carene epoxide, limonene diepoxide, as well as for two related compounds: 3-carene-5-one and 3-carene-2,5-dione. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
Библиографическая ссылка:
Fomenko V.V.
, Laev S.S.
, Salakhutdinov N.F.
Catalytic epoxidation of 3-carene and limonene with aqueous hydrogen peroxide, and selective synthesis of α-pinene epoxide from turpentine
Catalysts. 2021.
V.11. N4. 436
. DOI: 10.3390/catal11040436
WOS
Scopus
OpenAlex
Catalytic epoxidation of 3-carene and limonene with aqueous hydrogen peroxide, and selective synthesis of α-pinene epoxide from turpentine
Catalysts. 2021.
V.11. N4. 436
. DOI: 10.3390/catal11040436
WOS
Scopus
OpenAlex
Файлы:
Полный текст от издателя
Даты:
| Опубликована online: | 29 мар. 2021 г. |
Идентификаторы БД:
| Web of science: | WOS:000642858200001 |
| Scopus: | 2-s2.0-85103129986 |
| OpenAlex: | W3142934390 |