Catalytic epoxidation of 3-carene and limonene with aqueous hydrogen peroxide, and selective synthesis of α-pinene epoxide from turpentine Full article
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Catalysts
ISSN: 2073-4344 |
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| Output data | Year: 2021, Volume: 11, Number: 4, Article number : 436, Pages count : DOI: 10.3390/catal11040436 | ||
| Tags | 3-carene; 3-carene epoxide; Aqueous hydrogen peroxide; Epoxidation; Limo-nene; Limonene diepoxide; Turpentine; α-pinene; α-pinene epoxide | ||
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Abstract:
The epoxidation of turpentine (technical α-pinene), 3-carene, and limonene with aqueous hydrogen peroxide was studied in a new catalytic system employing manganese sulfate, salicylic acid, sodium bicarbonate, and acetonitrile, as a polar solvent. The proposed approach makes it possible to carry out a “chemical separation” of turpentine components, yielding valuable individual derivatives of monoterpenes without the need to isolate individual monoterpene reagents. Specific methods have been developed for the production of α-pinene epoxide, 3-carene epoxide, limonene diepoxide, as well as for two related compounds: 3-carene-5-one and 3-carene-2,5-dione. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
Cite:
Fomenko V.V.
, Laev S.S.
, Salakhutdinov N.F.
Catalytic epoxidation of 3-carene and limonene with aqueous hydrogen peroxide, and selective synthesis of α-pinene epoxide from turpentine
Catalysts. 2021.
V.11. N4. 436
. DOI: 10.3390/catal11040436
WOS
Scopus
OpenAlex
Catalytic epoxidation of 3-carene and limonene with aqueous hydrogen peroxide, and selective synthesis of α-pinene epoxide from turpentine
Catalysts. 2021.
V.11. N4. 436
. DOI: 10.3390/catal11040436
WOS
Scopus
OpenAlex
Files:
Full text from publisher
Dates:
| Published online: | Mar 29, 2021 |
Identifiers:
| Web of science: | WOS:000642858200001 |
| Scopus: | 2-s2.0-85103129986 |
| OpenAlex: | W3142934390 |