Crystal structure of pentafluoroacetanilide | Sciact - научная деятельность

Crystal structure of pentafluoroacetanilide Научная публикация

Журнал

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Вых. Данные

Год: 2015, Том: 56, Номер: 6, Страницы: 1201-1204 Страниц : 4 DOI: 10.1134/S002247661506030X

Ключевые слова

pentafluoroacetanilide; crystal structure; molecular structure; NMR

Авторы

Babailov S.P. ^1,2 , Stabnikov P.A. ¹ , Kuratieva N.V. ^1,2 , Nikulshin P.A. ³ , Gromilov S.A. ^1,2

Организации

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk Natl Res State Univ, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

A new compound C6F5N(H)C(O)CH3 pentafluoroacetanilide, which is promising for the formation of coordination compounds with metal cations, is synthesized. Its crystal structure is determined (APEX DUO diffractometer, lambda MoK (alpha), graphite monochromator, T = 150 K). Crystallographic data for C8H4F5NO are as follows: space group C2/c, a = 18.2460(7) , b = 10.5840(4) , c = 9.4489(4) , beta = 116.198(1)A degrees, V = 1637.28(11) (3), Z = 8. The compound has a molecular structure formed of isolated pentafluoroacetanilide molecules. The average distances in the phenyl ring are 1.39 for C-C and 1.34 for C-F. The molecular structure of the studied compound is confirmed by F-19 and H-1 NMR in the solution CCl4/CDCl3 = 1:1 (v:v).

Babailov S.P. , Stabnikov P.A. , Kuratieva N.V. , Nikulshin P.A. , Gromilov S.A.
Crystal structure of pentafluoroacetanilide
Journal of Structural Chemistry. 2015. V.56. N6. P.1201-1204. DOI: 10.1134/S002247661506030X WOS Scopus РИНЦ OpenAlex

Бабайлов С.П. , Стабников П.А. , Куратьева Н.В. , Никульшин П.В. , Громилов С.А.
Кристаллическая структура пентафторацетанилида

Журнал структурной химии (J STRUCT CHEM+). 2015. Т.56. №6. С.1256-1259. DOI: 10.15372/JSC20150630 РИНЦ OpenAlex

Опубликована в печати:	1 нояб. 2015 г.
Опубликована online:	23 янв. 2016 г.

Web of science:	WOS:000368734000030
Scopus:	2-s2.0-84955495843
РИНЦ:	26851187
OpenAlex:	W2411971398

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