Crystal structure of pentafluoroacetanilide

Crystal structure of pentafluoroacetanilide Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2015, Volume: 56, Number: 6, Pages: 1201-1204 Pages count : 4 DOI: 10.1134/S002247661506030X

Tags

pentafluoroacetanilide; crystal structure; molecular structure; NMR

Authors

Babailov S.P. ^1,2 , Stabnikov P.A. ¹ , Kuratieva N.V. ^1,2 , Nikulshin P.A. ³ , Gromilov S.A. ^1,2

Affiliations

1	(Данные Web of science) Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia
2	(Данные Web of science) Novosibirsk Natl Res State Univ, Novosibirsk, Russia
3	(Данные Web of science) Russian Acad Sci, Siberian Branch, Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

A new compound C6F5N(H)C(O)CH3 pentafluoroacetanilide, which is promising for the formation of coordination compounds with metal cations, is synthesized. Its crystal structure is determined (APEX DUO diffractometer, lambda MoK (alpha), graphite monochromator, T = 150 K). Crystallographic data for C8H4F5NO are as follows: space group C2/c, a = 18.2460(7) , b = 10.5840(4) , c = 9.4489(4) , beta = 116.198(1)A degrees, V = 1637.28(11) (3), Z = 8. The compound has a molecular structure formed of isolated pentafluoroacetanilide molecules. The average distances in the phenyl ring are 1.39 for C-C and 1.34 for C-F. The molecular structure of the studied compound is confirmed by F-19 and H-1 NMR in the solution CCl4/CDCl3 = 1:1 (v:v).

Babailov S.P. , Stabnikov P.A. , Kuratieva N.V. , Nikulshin P.A. , Gromilov S.A.
Crystal structure of pentafluoroacetanilide
Journal of Structural Chemistry. 2015. V.56. N6. P.1201-1204. DOI: 10.1134/S002247661506030X WOS Scopus РИНЦ OpenAlex

Бабайлов С.П. , Стабников П.А. , Куратьева Н.В. , Никульшин П.В. , Громилов С.А.
Кристаллическая структура пентафторацетанилида

Журнал структурной химии (J STRUCT CHEM+). 2015. Т.56. №6. С.1256-1259. DOI: 10.15372/JSC20150630 РИНЦ OpenAlex

Published print:	Nov 1, 2015
Published online:	Jan 23, 2016

Web of science:	WOS:000368734000030
Scopus:	2-s2.0-84955495843
Elibrary:	26851187
OpenAlex:	W2411971398

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