Synthesis of Derivatives of the Optically Active beta-Amino Acids from (+)-Car-2-ene

Synthesis of Derivatives of the Optically Active beta-Amino Acids from (+)-Car-2-ene Научная публикация

Журнал

Helvetica Chimica Acta
ISSN: 0018-019X , E-ISSN: 1522-2675

Вых. Данные

Год: 2008, Том: 91, Номер: 10, Страницы: 1849-1856 Страниц : DOI: 10.1002/hlca.200890197

Авторы

Koneva Ekaterina A. , Volcho Konstantin P. , Gatilov Yuri V. , Korchagina Dina V. , Salnikov Georgi E. , Salakhutdinov Nariman F.

Организации

1	(Данные Web of science) Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

The reaction of (+)-car-2-ene (4) with chlorosulfonyl isocyanate (=sulfuryl chloride isocyanate; CISO2NCO) led to the tricyclic lactams 6 and 8 corresponding to the initial formation both of the tertiary carbenium and alpha-cyclopropylcarbenium ions (Scheme 2). A number of optically active derivatives of beta-amino acids which are promising compounds for further use in asymmetric synthesis were synthesized from the lactams (see 16, 17, and 19-21 in Scheme 3).

Koneva E.A. , Volcho K.P. , Gatilov Y.V. , Korchagina D.V. , Salnikov G.E. , Salakhutdinov N.F.
Synthesis of Derivatives of the Optically Active beta-Amino Acids from (+)-Car-2-ene
Helvetica Chimica Acta. 2008. V.91. N10. P.1849-1856. DOI: 10.1002/hlca.200890197 WOS Scopus РИНЦ

Опубликована в печати:

1 окт. 2008 г.

Web of science	WOS:000261050300004
Scopus	2-s2.0-55249104742
РИНЦ	13567262
OpenAlex	W2038120370