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Perfluorinated Europium(III) Carboxylates: Synthesis and Properties Научная публикация

Журнал Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
ISSN: 1070-3284
Вых. Данные Год: 1997, Том: 23, Номер: 6, Страницы: 432-438 Страниц : 7
Авторы Larionov S.V. 1 , Kirichenko V.N. 1 , Rastorguev A.A. 1 , Belyi V.I. 1 , Sheludyakova L.A. 1 , Fadeeva V.P. 2 , Karpov V..M. 2 , Platonov V.E. 2 , Batrachenko N .I. 2 , Lisoivan V..I. 2
Организации
1 Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
2 Russian Acad Sci, Novosibirsk Organ Chem Inst, Siberian Div, Novosibirsk 630090, Russia

Реферат: Perfluoroaliphatic and perfluoroaromatic europium(III) carboxylates Eu(RCO2)(3) center dot nH(2)O, where R = CF3 or CF3CF2 and n = 3; R = CF3CF2CF2 or CF3CF2CF2CF2 and n = 2; R = C6F5 and n = 1; and R = 4-CF3C6F4 and n = 2, are synthesized. The mu(eff) values of these compounds are equal to 3.1-3.2 mu B. The compounds are studied by luminescence, IR spectroscopy, and vapor-phase osmometry methods. The thermolysis of perfluorinated europium(III) carboxylates at relatively low temperatures results in the formation of EuF3.
Библиографическая ссылка: Larionov S.V. , Kirichenko V.N. , Rastorguev A.A. , Belyi V.I. , Sheludyakova L.A. , Fadeeva V.P. , Karpov V.M. , Platonov V.E. , Batrachenko N.I. , Lisoivan V.I.
Perfluorinated Europium(III) Carboxylates: Synthesis and Properties
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 1997. V.23. N6. P.432-438. WOS
Идентификаторы:
Web of science WOS:000207438800011